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Wettability of the Organic Bentonite Modified by MDFFA Mixed With  Other Alkyl Quaternary Ammonnium Salts
HAN Fan-zhen, GAO Mang-lai*, LIU Yong-bin
Abstract337)      PDF (2947KB)(335)      
 
Washburn method was applied to investigate on the wettability of the organic bentonite modified by molecular deposition filming flooding agent (MDFFA) mixed with tetraethyl ammonium bromide [(Et) 4NB], dodecyl trimethyl ammonium bromide (DTAB) or hexadecyl trimethyl ammonium bromide (CTAB). The results show that the organic bentonite absorbed MDFFA is more hydrophilic than that of organic bentonite absorbed (Et) 4NB,DTAB,CTAB, then the oil wettability of organic bentonite absorbed MDFFA is lower than others. For the solution of MDFFA mixed with (Et) 4NB,DTAB or CTAB, with the increase of MDFFA volume proportion the organic bentonite is more hydrophilic and the oil wettability is lower, especially for the organic bentonite treated by the solution of MDFFA mixed with (Et) 4NB, when (Et) 4NB mixed with a little MDFFA the organic bentonite is more hydrophilic than that of absorbed (Et) 4NB and the oil wettability is lower obviously.
2008, 21 (1): 21-24.
The Aqueous Solution Property of MDFFA/SDS Mixed System
YANG Li, GAO Mang-lai, LIU Hong-sheng, HAN Fan-zhen
Abstract408)      PDF (1154KB)(379)      
Critical micelle concentration (cmc) of molecular deposition filming flooding agent (MDFFA) and sodium dodecyl sulfate (SDS) mixed systems were determined by conductivity method, and the effect of MDFFA on the precipitating behavior of anionic surfactant and multivalent cation was studied by means of light transmission measurement. The results show that MDFFA can decrease the cmc of SDS, the cmc decreases with the increasing of the concentration of MDFFA. With the increasing of temperature from 25 ℃ to 50 ℃, the cmc of  2 mmol/L MDFFA/SDS mixed system decreased. The cmcof 2 mmol/L MDFFA/SDS decreased with the increasing of concentration of NaCl. The precipitating behavior did not happen when MDFFA and SDS were mixed. MDFFA can restrain the precipitating behavior of anionic surfactant and Ca 2+. The capability of MDFFA restrain the precipitating behavior is better than NaCl, NaOH and NaHCO 3.
2007, 20 (4): 33-37.